The demands of the modern automotive industry
are ever challenging – users want high performance cars and at the same time
are looking for improved reliability and safety, greater comfort, fuel efficiency,
style and competitive pricing. Plastics’ versatility in automotive industry
allows them for advanced shapes and forms without compromising on the safety,
comfort or stability of a car, thus making them a very attractive resource for
designers.
There is one product of plastics family that
is rising to the challenge of these potentially conflicting demands- IMPACT
MODIFIERS. Technological innovation by the plastics industry is a key feature
in the continuing development and use of impact modifiers in the automotive
segment. With their unique combination of properties, Impact modifiers have
become the key in providing enhanced performance with cost-efficiency and
sustainability in mind.
Engineering polymers have been used
extensively in automobiles in a variety of applications such as grille opening
retainers, bumpers, trim panels, radio housing, door outer panel, handle, fog
light cover, decorative panels, fuel tank etc. Originally polymers were
specified because they offered good mechanical properties combined with
excellent appearance, including the possibility of self-coloring but now
general grade polymers are used along with some speciality additives like
Impact Modifiers. The use of Impact modifiers in general grade polymers has
proved their substitution for Engineering Polymers. Commodity polymers like PE,
PP, PVC etc. are tremendously being used in large automotive parts where these
must meet the performance requirements and Impact modifiers make it possible.
Stiffness and toughness are two inherent
functions of an Impact Modifier. It is also the main additive for increasing
flexibility and impact strength to meet physical property requirements of rigid
parts. It also exhibits the property which increases the durability of molded
or extruded plastics, particularly those subject to impact forces or cold
weather service. A broad range of impact modifiers are available for toughened
nylon resins, as well as for rigid PVC, PBT, ABS and other commonly specified
plastics depending on the host polymer and the required properties. The most
commonly used Impact modifiers for engineering polymers like Nylon, PBT, PC
etc. are maleic anhydride grafted polymers which impart a degree of elasticity
in otherwise brittle polymers. These impact modifiers apart from improving
mechanical properties also improve processability.
In recent years, increased safety and comfort
features have led to a slight rise in the overall weight of the average car from
1015 kg in 1990 to 1132 kg in 1998. But plastics components have ensured that
the balance between safety and lightweight efficiency is maintained by consistently
reducing weight without compromising safety features. This has been made
possible by Impact Modifiers only. It is estimated that if the traditional
materials were to be used in place of impact modified plastics, today’s cars would
be at least 200kg heavier resulting in increased fuel consumption.
Some unmodified polymers such as rigid
polyvinyl chloride (PVC), polystyrene (PS) or styrene acrylonitrile (SAN) are brittle
at ambient temperatures. Others such as polyamides or polyolefins are ductile
at ambient temperature but become brittle at low temperatures. Some, such as
polycarbonate (PC), may have good dart impact but poor notch impact resistance.
An impact modifier is needed whenever the polymer system does not meet the
impact requirements for a particular application.
A variety of impact modifiers are available
depending on the host polymer and the required properties. Styrenic impact
modifiers are growing at an AAGR of less than 3%, while other types are growing at rates of 5-6%. Since PVC is
the largest user of impact modifiers, consuming about 80% of the volume, growth
of impact modifiers is tied to PVC use. Engineering resins such as PC, polyamides,
and polyesters, which consume about 10% of impact modifier volume, are growing
strongly, boosting impact modifier use. Polyolefins consume the remaining 10%
of impact modifier volume. The continuing trend towards ‘better, cheaper,
faster’ is helping drive use of impact modifiers, which can be used to either
improve properties or maintain properties of thinner parts.
Looking forward to the 21st
century, the ongoing development of advanced, high-performance additives has
dramatically increased the usage of plastics in the industry. With this the
automotive industry is on the brink of a revolution, and the plastics industry
poised to play a major role. Thanks to plastics & speciality additives, the
cars we dream of today are quickly being developed – offering high performance,
cleaner driving and advanced safety and convenience features.
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